Blue-white Rigel shines as the brightest star in the constellation Orion the Hunter. It's a hot massive star, that someday will explode as a supernova.
The 6th-brightest star in the night sky, Capella, in the Northern Hemisphere constellation Auriga the Charioteer, is also a point of the Winter Hexagon.
Aldebaran, the brightest star in Taurus the Bull, is at one tip of a V-shaped cluster. If placed where our sun is, its surface would pass the orbit of Mercury.
What's the scariest star in all the heavens? Look for Algol the Demon Star on autumn evenings. It's a great choice for a driveway telescope night on Halloween.